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The title compound, [Ce(C12H14F3O2)2(C6H18NSi2)(C6H15N3)], is a rare example of a structurally characterized lanthanide(III) camphorate. The CeIII atom shows a distorted trigonal–dodeca­hedral coordination, formed by the N atom of the amido ligand [Ce—N = 2.428 (5) Å], four O atoms of two η2-bonded camphorate groups [average Ce—O = 2.459 (4) Å] and three N atoms of a chelating triaza­cyclo­hexa­ne donor [average Ce—N = 2.808 (6) Å].

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The title dimeric aluminium amide, [Al2(CH3)4(C6HF5N)2], contains a folded Al2N2 ring with four-coordinate Al atoms [mean Al—N = 1.9910 (14) Å and mean Al—C = 1.9452 (19) Å]. The penta­fluoro­phen­yl substituents on the N atoms adopt a trans configuration.

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In the crystalline state, the mol­ecule of the title compound, (+)-(1R,4R)-3-(hydr­oxybenzyl­idene)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one, C17H20O2, exists in the enolized form, with the H atom located on the phenyl-substituted C—O fragment rather than on the camphoryl-substituted one. The enolic H atom is involved in intra­molecular hydrogen bonding [O...O = 2.633 (2) Å].
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