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The title compound, (C10H9N2)[Fe(C7H3NO4)2]·3H2O, was prepared from the ligand pyridine-2,6-dicarboxylic acid with FeCl3·6H2O in the presence of 2,2-bipyridine. The FeIII atom is six-coordinate in a distorted octa­hedral geometry. The compound contains protonated 2,2′-bipyridine and doubly deprotonated pyridine-2,6-dicarboxyl­ate (pydc) units; the protonated 2,2′-bipyridine bridges adjacent [Fe(pydc)2] complex units through hydrogen bonding.
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