5-[(1H-1,2,4-Yriazol-1-yl)meth­yl]-4-(4-fluoro­benzylidene­amino)-2H-1,2,4-triazole-3(4H)-thione

In the title compound, C₁₂H₁₀FN₇S, the dihedral angles made by the plane of the thione-substituted triazole ring with the planes of the other triazole ring and the benzene ring are 71.94 (3) and 40.10 (2)°, respectively. Inter- and intra­mol­ecular hydrogen-bond and π–π stacking inter­actions stabilize the structure.

4-(4-Chloro­benzyl­ideneamino)-3-(1H-1,2,4-triazol-1-ylmeth­yl)-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C₁₂H₁₀ClN₇S, the dihedral angles made by the plane of the thione-substituted triazole ring with the planes of the other triazole ring and the benzene ring are 73.57 (3) and 46.65 (2)°, respectively. Inter- and intra­molcular hydrogen bonds and π-π stacking inter­actions stabilize the structure.

4-(2-Hydroxy­benzyl­ideneamino)-3-(1H-1,2,4-triazol-1-ylmeth­yl)-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C₁₂H₁₁N₇OS, the dihedral angles made by the thione-substituted triazole ring with the other triazole ring and the benzene ring are 71.56 (2) and 47.89 (3)°, respectively. Inter- and intra­molcular hydrogen-bond inter­actions stabilize the structure.