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The asymmetric unit of the title complex, [Cu(C3H4N2)4(H2O)2][Cu(C8H2NO6)(C3H4N2)3]2·2H2O, contains half of a centrosymmetric diaqua­tetra­kis­(1H-imidazole)copper(II) cat­ion and a complex anion comprising copper(II) coord­inated by a pyridine-2,4,6-tricarboxyl­ate anion and three imidazole ligands, together with a water molecule.

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The crystal structure of the title compound, C29H39N3O4S4, was determined at 97 K and possesses normal geometric parameters.
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