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The structure of the title compound, [Al2(CH3)4(C10H12NO)2] or [Me2Al{μ-(2,6-Me2C6H3)NCMeO}]2, consists of a four-coordinate dimeric centrosymmetric eight-membered ring Al-containing species.

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The structure of the centrosymmetric title compound, [(4-F-C6H4NH2)2(MeCN)2NiBr2] or [NiBr2(C6H6FN)2(C2H3N)2], reveals each of the pairs of bromide, acetonitrile and 4-fluoro­aniline ligands arranged trans to each other with a near octa­hedral geometry at the Ni atom.
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