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The title compound, C33H25N·0.25C6H14, was synthesized via the Ullmann reaction. The dihedral angles between the planes of the phen­yl rings of the diphenyl­amine group and the plane of the central benzene ring are 109.2 (3) and 114.1 (8)°.

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Two compounds were obtained via the addition of N-methyl­hydroxy­lamine to 1-phenyl-2-nitropropene. The structure of the major product, the title compound, (I), C17H17N3O6, is reported here. Both asymmetric C atoms (C1 and C2) have the same chirality, either R,R or S,S.

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The title compound, C22H20N2O3, was prepared by the reaction of 4-benz­yloxy-3-methoxy­benzaldehyde and benzohydrazide. The central vanillin system makes dihedral angles of 18.2 (1) and 14.3 (1)° with the planes of the benzohydrazide and benzyl groups, respectively. The crystal structure is stabilized by inter­molecular N—H...O hydrogen bonding.

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The title compound, C17H19Cl2N2OS+·Cl, was synthesized from 2-acetothio­phene, 1-(2,3-dichloro­phen­yl)piperazine and paraformaldehyde. In the cation, the thienyl ring is coplanar with the oxopropyl group. The protonated piperazine ring exhibits a chair conformation. In the crystal packing the cations are connected by C—H...O and C—H...Cl hydrogen bonds.
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