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The title compound, C10H10N6OS, was synthesized by the reaction of 1H-1,2,4-triazol-3-yl­hydrazine with phenyl isocyanate in benzene. The mol­ecule is non-planar, the dihedral angle between the two aromatic rings being 62.07 (7)°. N—H...O, N—H...N and N—H...S hydrogen bonds are observed.

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The title compound, C20H14N12S2, was synthesized by the reaction of 3-hydrazino-1H-1,2,4-triazole with phenyl isocyanate in benzene and by ring closure in an alkaline medium. Intermolecular N—H...N hydrogen bonds are observed and these form a five-membered ring.

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In the crystal structure of the title compound, C10H9N5O2, inter­molecular N—H...N [H...N = 2.13 (2) Å] and N—H...O [H...O = 2.016 (18) and 2.05 (2) Å] hydrogen bonds link mol­ecules into a two-dimensional framework.

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The crystal structure of the title compound, C18H15Br2N3O2, shows a strong intra­molecular O—H...N hydrogen bond [N...O = 2.609 (4) Å, O—H = 0.90 Å, H...N = 1.80 Å and O—H...N = 148°], which leads to the existence of a phenol–imine tautomer.
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