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The title compound, C21H16N4Cl2, was prepared by the reaction of 4-(2,6-dichloro­benzyl­idenamino)-3,5-diphenyl-4H-1,2,4-triazole and NaBH4. The supramolecular structure is defined by N—H...N and C—H...N hydrogen bonds, π–π stacking and C—H...π interactions.

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The title compound, C24H24N4O3, contains three aromatic rings and a triazole ring which are not coplanar. In the crystal structure the mol­ecules are linked by C—H...N, C—H...O, N—H...N, C—H...π and π–π interactions.

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The mol­ecule of the title compound, C12H20N6O2·2H2O, contains two planar triazole rings. The mol­ecule has crystallographic twofold rotation symmetry. The crystal structure is stabilized by inter­molecular hydrogen bonds, which form a three-dimensional network.
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