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The title compound, C6H6N4S, crystallizes with two independent mol­ecules, A and B, in the asymmetric unit. Both independent mol­ecules are almost planar [maximum deviations of 0.068 (6) Å in mol­ecule A and 0.079 (6) Å in mol­ecule B]. In the crystal, mol­ecules A and B are linked by N—H...S, N—H...N and C—H...S hydrogen bonds, forming a three-dimensional network.
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