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In the title compound, C13H10O4·H2O, both the carboxylic acid [Car-Car-C-O = -121.1 (2)°, where ar = aromatic] and the ester [Car-Car-O-C = -104.4 (3)°] groups lie out of the mean plane of the conjugated aromatic system. In the crystal, the organic mol­ecule is hydrogen bonded to water mol­ecules through the ester and carb­oxy moieties, forming chains along the a-axis direction. The methyl H atoms of the acet­oxy group are disordered over two equally occupied sites.

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In the title compound, C11H10N2O3, which is a potential bioactive compound, the benzene and oxa­diazole rings are approximately coplanar, with an inter-ring dihedral angle of 4.14 (2)°, while the ester plane is rotated out of the benzene plane [dihedral angle = 82.69 (9)°]. In the crystal, the mol­ecules form layers down the a axis with weak π–π inter­actions between the oxa­diazole and benzene rings [minimum ring centroid separation = 3.7706 (14) Å].
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