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In the title compound, C6H4N4S3, the 1,3,4-thia­diazole ring is essentially planar, with an r.m.s. deviation of 0.001 Å. The two N—C—S—C torsion angles in the mol­ecule are −23.41 (15) and 0.62 (14)°. One aceto­nitrile group is above the plane of the 1,3,4-thia­diazole ring and the other is below it, indicating syn and anti orientations. In the crystal, C—H...N hydrogen bonds link the molecules into ribbons along [010].
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