metal-organic compounds
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The title compound, [Cu2Cl4(C7H8N2O)2], crystallizes as discrete [CuLCl2]2 (L = 2-aminobenzamide) dimers with inversion symmetry. Each CuII ion is five-coordinated and is bound to two bridging chloride ligands, a terminal chloride ligand and a bidentate 2-aminobenzamide ligand. The crystal structure exhibits alternating layers parallel to (010) along the b-axis direction. In the crystal, the components are linked via N—HCl hydrogen bonds, forming a three-dimensional network. These interactions link the molecules within the layers and also link the layers together and reinforce the cohesion of the structure.
metal-organic compounds
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The title compound, [Co2(C8H7O2)4(C7H10N2)2], crystallizes as a centrosymmetric dimer containing two CoII atoms bridged by four bidentate phenylacetate ligands in syn–syn bridging modes. Each CoII atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—HO interactions link the dinuclear complex molecules into a three-dimensional network.
organic compounds
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In the crystal structure of the title salt hydrate, C9H8NO+·HSO4−·H2O, the quinoline N—H atoms are hydrogen bonded to the bisulfate anions. The bisulfate anions and water molecules are linked together by O—HO hydrogen-bonding interactions. The cations and anions form separate layers alternating along the c axis, which are linked by N—HO and O—HO hydrogen bonds into a two-dimensional network parallel to (100). Further O—HO contacts connect these layers, forming a three-dimensional network, in which two R44(12) rings and C22(13) infinite chains can be identified.
organic compounds
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In the title Schiff base salt, C16H13N2O+·ClO4−, the pyridine ring and the naphthalene ring system are approximately co-planar [making a dihedral angle of 6.05 (12)°] and an intramolecular O—HN hydrogen bond occurs between the hydroxyl and imino groups. In the crystal, the cations and anions are linked by N—HO and weak C—HO hydrogen bonds, forming the supramolecular layers parallel to (100). The crystal studied was an inversion twin refined with minor component = 0.43 (13).