organic compounds
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The title compound, C24H19ClN2, crystallizes with two independent molecules in the asymmetric unit. The prop-2-enyl substituents on the imidazole rings adopt similar conformations in the two molecules. The 4-and 5-substituted phenyl rings and the benzene ring make dihedral angles of 67.06 (8), 5.61 (8) and 41.09 (8)°, respectively, with the imadazole ring in one molecule and 71.53 (8), 28.85 (8) and 41.87 (8)°, respectively, in the other. The crystal structure features C—Hπ interactions and weak π–π stacking interactions [centroid–centroid distances = 3.6937 (10) and 4.0232 (10) Å] between the chlorophenyl rings, which form a three-dimensional supramolecular structure.
organic compounds
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The asymmetric unit of the title compound, C16H13N3O3·0.5C2H6OS, is composed of two independent pyrazolidine-3,5-dione molecules and one dimethyl sulfoxide solvent molecule. In each pyrazolidine-3,5-dione molecule, an intramolecular N—HO hydrogen bond forms an S(5)S(6) motif. In the crystal, pairs of each independent pyrazolidine-3,5-dione molecule are linked by N—HO hydrogen bonds, forming dimers with R22(8) motifs. These dimers are connected with the other molecules through the solvent molecules via O—HO hydrogen bonds, forming ribbons along the b-axis direction. C—Hπ interactions connect the ribbons. C—HO interactions also occur.
organic compounds
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The asymmetric unit of the title salt, C8H10N5+·C7H7O3S−, consists of two amino[(1H-benzimidazol-2-yl)amino]methaniminium cations and two 4-methylbenzenesulfonate anions. The cations are each stabilized by intramolecular N—HN hydrogen bonds between the free amino groups and the imine N atoms of the benzimidazole units, forming S(6) ring motifs. In the crystal, cations and anions are linked by N—HO and C—HO hydrogen bonds, forming a three-dimensional supramolecular framework. Two strong π–π stacking interactions [centroid–centroid distances = 3.4112 (14) and 3.4104 (14) Å] also occur between the centroids of the imidazole rings of like cations.
organic compounds
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In the title compound, C20H20N2O3, the central 2,5-dihydro-1H-pyrrole ring [r.m.s. deviation = 0.014 (1) Å] is oriented at dihedral angles of 77.81 (6) and 25.33 (6)°, respectively, to the attached phenyl ring and the aniline phenyl ring. An intramolecular N—HO hydrogen bond occurs. In the crystal, molecules are linked through pairs of N—HO hydrogen bonds, forming inversion dimers with an R22(10) ring motif. Two weak C—Hπ interactions are also observed.
organic compounds
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In the title compound, C20H18Cl2N2O3, the dihedral angles between the central 2,5-dihydro-1H-pyrrole ring and the phenyl rings are 74.87 (9) and 29.09 (9)°. Intramolecular N—HO and C—HO hydrogen bonds occur. In the crystal, pairs of N—HO hydrogen bonds link adjacent molecules into inversion dimers and form an R12(6)R22(10)R12(6) ring motif through C—HO hydrogen bonds.