organic compounds
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In the title compound, C13H11N3S2, the triazole and thiophene rings are coplanar [dihedral angle = 6.22 (13)°]. By contrast, the phenyl ring is perpendicular to the triazole ring [dihedral angle = 85.58 (13)°], so that the molecule has an L-shape. The thiophene S atom is syn with the ring imine N atom. In the crystal, eight-membered {HNCS}2 synthons form between centrosymmetrically related molecules, leading to dimeric aggregates that are connected into a supramolecular layer parallel to (101) by π–π interactions between centrosymmetrically related triazole rings [centroid–centroid distance = 3.6091 (15) Å] and C—Hπ interactions.