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In the title compound, C21H22O2S, the cyclopentyl ring adopts an envelope conformation with the flap atom connected to the benzofuran residue. The benzofuran unit is essentially planar, with a mean deviation from the least-squares plane defined by the nine constituent ring atoms of 0.008 (2) Å. In the crystal, molecules are linked via pairs of C—H
π interactions, forming inversion dimers. In the ring of the 4-methylphenyl group, four C atoms and their attached H atoms are disordered over two sets of sites, with site-ccupancy factors of 0.899 (5) and 0.10.
π interactions, forming inversion dimers. In the ring of the 4-methylphenyl group, four C atoms and their attached H atoms are disordered over two sets of sites, with site-ccupancy factors of 0.899 (5) and 0.10.organic compoundsOpen access
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There are two symmetry-independent molecules, A and B, in the asymmetric unit of the title compound, C17H14FIO3S. The dihedral angle formed by the 4-fluorophenyl ring and the mean plane [r.m.s. deviation = 0.013 (2) Å in molecule A and 0.016 (2) Å in molecule B] of the benzofuran fragment is 57.71 (7)° in molecule A and 44.95 (7)° in molecule B. In the crystal, molecules are linked by weak C—HO hydrogen bonds and IO contacts [IO = 3.3646 (15) and 3.2354 (14) Å], forming a three--dimensional network.
O hydrogen bonds and IO contacts [IO = 3.3646 (15) and 3.2354 (14) Å], forming a three--dimensional network.organic compoundsOpen access
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In the title compound, C16H12BrFO3S, the 4-fluorophenyl ring makes a dihedral angle of 72.35 (5)° with the mean plane [r.m.s. deviation = 0.008 (1) Å] of the benzofuran fragment. In the crystal, molecules are linked into [010] chains via two different inversion-generated pairs of C—HO hydrogen bonds. The crystal structure also exhibits slipped π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.667 (2) Å and slippage = 1.341 (2) Å], and between the benzene and the furan rings of neighbouring molecules [centroid–centroid distance = 3.759 (2) Å and slippage = 0.757 (2) Å].
O hydrogen bonds. The crystal structure also exhibits slipped π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.667 (2) Å and slippage = 1.341 (2) Å], and between the benzene and the furan rings of neighbouring molecules [centroid–centroid distance = 3.759 (2) Å and slippage = 0.757 (2) Å].organic compoundsOpen access
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In the title compound, C20H12BrFO2S, the dihedral angles between the mean plane [r.m.s. deviation = 0.006 (2) Å] of the benzofuran fragment and the pendant 4-fluorophenyl and phenyl rings are 84.98 (5) and 40.98 (6)°, respectively. In the crystal, molecules are linked by C—HO and C—Hπ interactions.
O and C—Hπ interactions.
