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In the title compound, C14H10ClNO2, obtained by the condensation of 4-chloroaniline and piperonal, the five-membered ring is almost planar (r.m.s. deviation = 0.023 Å) and the dihedral angle between the aromatic rings is 43.22 (14)°. In the crystal, a short OCl contact of 3.173 (2) Å is observed. The molecules are arranged into corrugated (010) layers.