data reports
Open access
In the title compound, C10H9N3O3S, the five-membered ring adopts a slightly twisted conformation about the Cm—S (m = methylene) bond. The dihedral angle between this ring and the benzene ring is 7.99 (9)°. A bifurcated intramolecular N—H(O,S) hydrogen bond helps to establish the near planar conformation of the molecule. In the crystal, molecules are linked by N—HO and O—HO hydrogen bonds to generate (001) sheets.
data reports
Open access
In the title compound, C11H11N3O3S·3H2O, the non-H atoms of the main molecule are approximately planar, with an r.m.s. deviation of 0.030 Å. There is a bifurcated intramolecular N—H(O,S) hydrogen bond present forming S(6) and S(5) ring motifs. In the crystal, O—HO and N—HO hydrogen bonds link the molecules into a three-dimensional network.