data reports
Open access
In the title molecule, C14H13NO2, the dihedral angle between the planes of the benzene rings is 65.18 (4)°. The central amide group has about the same degree of twist with respect to both ring planes, as indicated by the dihedral angles of 34.70 (8) and 30.62 (8)° between its plane and that of the phenyl and 4-methoxybenzene rings, respectively. The C atom of the methoxy group is close to being coplanar with its attached ring [deviation = −0.112 (2) Å]. In the crystal, molecules are linked by inter-amide N—HO hydrogen bonds, which generate C(4) chains propagating in the [100] direction. Adajcent molecules in the chain are related by translational symmetry.
data reports
Open access
In the title compound, C10H9N3O3S, the five-membered ring adopts a slightly twisted conformation about the Cm—S (m = methylene) bond. The dihedral angle between this ring and the benzene ring is 7.99 (9)°. A bifurcated intramolecular N—H(O,S) hydrogen bond helps to establish the near planar conformation of the molecule. In the crystal, molecules are linked by N—HO and O—HO hydrogen bonds to generate (001) sheets.