organic compounds
Open access
In the title compound, C14H13NO3, the dihedral angles between the central pyrrolidine ring and the pendant tetrahydrofuran and phenyl rings are 5.34 (18) and 58.99 (17)°, respectively. The tetrahydrofuran ring is almost planar (r.m.s. deviation = 0.008 Å). In the crystal, molecules are linked by C—HO interactions, generating a three-dimensional network.
organic compounds
Open access
In the title molecular salt, C22H21FI+·CF3SO3−, the dihedral angle between the rings of the biphenyl group is 65.6 (1)°. The ring of the mesitylene group is inclined to the fluorobenzene ring at an angle of 86.1 (3)° and the C—I—C bond angle is 97.0 (2)°. In the crystal, extremely short IO contacts of 2.862 (5) and 2.932 (5) Å occur, due to the strong electrostatic interactions between the I atom and two adjacent trifluoromethanesulfonate counter-ions. There are also C—HF and C—Hπ interactions present: together with the IO bonds, these result in a three-dimensional network.