organic compounds
Open access
The asymmetric unit of the title compound, C13H11ClN4O2S, contains two molecules (A and B), in which the dihedral angles between the 1H-imidazo[4,5-c]pyridine system and terminal phenyl ring are 80.83 (10) and 62.34 (1)°. In the crystal, A–B dimers are linked by pairs of N—HN hydrogen bonds, which generate R22(10) loops. The dimers are linked by C—HO and C—HCl interactions, generating a three-dimensional network. Aromatic π–π stacking interactions [shortest centroid–centroid distance = 3.5211 (12) Å] are also observed.
organic compounds
Open access
In the title compound, C26H18F4O2, the dihedral angles between pairs of benzene rings linked to the same C atom are 80.55 (8) and 79.11 (7)°. The crystal packing features C—Hπ interactions and shows stacking when viewed along the c axis.