organic compounds
Open access
In the title compound, C19H17N5S, the dihedral angles between the purine ring system (r.m.s. deviation = 0.009 Å) and the S-bound and methylene-bound phenyl rings are 74.67 (8) and 71.28 (7)°, respectively. In the crystal, inversion dimers linked by pairs of N—HN hydrogen bonds generate R22(8) loops. C—HN interactions link the dimers into (100) sheets.
metal-organic compounds
Open access
The asymmetric unit of the title compound, [Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldiphenylphosphane ligand is the longest of the three Ru—Ru bonds in both molecules. In the crystal, molecules are linked by C—HO hydrogen bonds, forming layers parallel to the ac plane. C—Hπ contacts further stabilize the crystal packing.
Keywords: crystal structure.
data reports
Open access
In the title compound, [SbBr(C10H7)2], the SbIII atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intramolecular C—HBr hydrogen bond forms an S(5) ring motif. In the crystal, weak C—HBr interactions link the molecules into helical chains along the b-axis direction.