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In the title compound, C21H26O2SSe, the S atom adopts a pyramidal geometry (bond-angle sum = 304°) and the n-butyl chain shows an extended conformation. An intra­molecular C—H...O hydrogen bond closes an S(8) ring. In the crystal, inversion dimers are formed with molecules linked by pairs of O—H...O=S hydrogen bonds, generating R22(14) loops. Weak C—H...O inter­actions also occur.

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In the title mol­ecular salt, C12H12N22+·2C7H5O5S, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carb­oxy­lic acid group and the benzene ring is 12.41 (11)°. In the crystal, the anions are linked into inversion dimers by pairs of O—H...O hydrogen bonds, which generate R22(16) loops. The dications link the anion dimers into [10-2] chains via N—H...O hydrogen bonds.
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