organic compounds
Open access
In the title compound, C21H26O2SSe, the S atom adopts a pyramidal geometry (bond-angle sum = 304°) and the n-butyl chain shows an extended conformation. An intramolecular C—HO hydrogen bond closes an S(8) ring. In the crystal, inversion dimers are formed with molecules linked by pairs of O—HO=S hydrogen bonds, generating R22(14) loops. Weak C—HO interactions also occur.
data reports
Open access
In the title molecular salt, C12H12N22+·2C7H5O5S−, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carboxylic acid group and the benzene ring is 12.41 (11)°. In the crystal, the anions are linked into inversion dimers by pairs of O—HO hydrogen bonds, which generate R22(16) loops. The dications link the anion dimers into [10-2] chains via N—HO hydrogen bonds.