organic compounds
Open access
The complete molecule of the title compound, C32H28N2, is generated by crystallographic inversion symmetry. The dihedral angles between the central aromatic ring and the pendant adjacent rings are 61.37 (16) and 74.20 (14)°. The N—H group does not participate in hydrogen bonds and there are no aromatic π–π stacking interactions in the crystal.
organic compounds
Open access
In the title compound, C22H18Cl2N2O, the indazole ring system is approximately planar [maximum deviation = 0.031 (2) Å], its mean plane is oriented at 3.17 (4) and 19.34 (4)° with respect to the phenyl and benzene rings. In the crystal, weak C—Hπ interactions link the molecules into supramolecular chains running along the b-axis direction.
organic compounds
Open access
The asymmetric unit of the title compound, C13H10N2O2, contains two crystallographically independent molecules (A and B). The indazole ring systems are approximately planar [maximum deviations = 0.0037 (15) and −0.0198 (15) Å], and their mean planes are oriented at 80.10 (5) and 65.97 (4)° with respect to the furan rings in molecules A and B, respectively. In the crystal, pairs of C—HN hydrogen bonds link the B molecules, forming inversion dimers. These dimers are bridged by the A molecules via C—HO hydrogen bonds, forming sheets parallel to (011). There are also C—Hπ interactions present, and π–π interactions between neighbouring furan and the indazole rings [centroid–centroid distance = 3.8708 (9) Å] of inversion-related molecules, forming a three-dimensional structure.