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metal-organic compounds
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In the title compound, [Sn(C6H5)3(C5H8NS2)], the SnIV atom adopts a distorted SnC3S tetrahedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intramolecular Sn
S contact [3.0270 (9) Å] occurs and two intramolecular C—HS interactions help to establish the conformation. Three of the methylene groups of the pyrrolidine-1-carbodithioate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C—HS interactions link the molecules into a three-dimensional network, with both S atoms acting as acceptors.
S contact [3.0270 (9) Å] occurs and two intramolecular C—HS interactions help to establish the conformation. Three of the methylene groups of the pyrrolidine-1-carbodithioate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C—HS interactions link the molecules into a three-dimensional network, with both S atoms acting as acceptors.organic compoundsOpen access
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In the title compound, C11H11NO3, the dihydrofuran-2,5-dione ring has a shallow envelope conformation, with one of the methylene C atoms displaced by 0.216 (1) Å from the other atoms. These near-planar atoms subtend a dihedral angle of 55.88 (8)° with the benzene ring. In the crystal, C—HO hydrogen bonds link the molecules into [010] chains.
O hydrogen bonds link the molecules into [010] chains.
