metal-organic compounds
Open access
In the title compound, [Sn(C6H5)3(C2H3OS2)], the SnIV atom adopts a distorted SnC3S tetrahedral coordination geometry. A short SnO contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).
organic compounds
Open access
In the title compound, C15H15NO2, the dihedral angle between the aromatic rings is 5.86 (6)°, and an intramolecular N—HO hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intramolecular O—HO hydrogen bond also occurs. In the crystal, inversion dimers linked by pairs of O—HO hydrogen bonds generate R22(10) loops. A C—HO interaction links the dimers into [010] chains and aromatic π–π stacking [centroid–centroid separation = 3.6131 (9) Å] also occurs.