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In the title mol­ecular salt, C5H9N2+·C7H3N2O7, the roughly planar anion (r.m.s. deviation = 0.120 Å) has been deprotonated at the phenol group. An intra­molecular O—H...O hydrogen bond in the anion generates an S(6) ring. In the crystal, the components are linked by cation-to-anion N—H...O and N—H...(O,O) hydrogen bonds, generating [010] double chains. Weak C—H...O inter­actions consolidate the packing.
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