metal-organic compounds
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In the title coordination polymer, [Hg2Cl4(C26H20N6)]n, one HgII ion is coordinated by four N atoms from the benzylbis((pyridin-2-yl)methylidenehydrazone) ligand and two Cl− ions in a very distorted cis-HgCl2N4 octahedral geometry. The other HgII ion is coordinated in a distorted tetrahedral geometry by four Cl− ions. Bridging chloride ions link the HgII ions into a chain propagating in [010]: the Hg—Cl bridging bonds are significantly longer than the terminal bonds. The dihedral angle between the central benzene rings of the ligand is 83.3 (2)°. The packing is consolidated by weak C—HCl hydrogen bonds and C—Hπ interactions.