3-(Adamantan-1-yl)-4-(prop-2-en-1-yl)-1H-1,2,4-triazole-5(4H)-thione

The title mol­ecule, C₁₅H₂₁N₃S, exists as the thione tautomer in the solid state. The 1,2,4-triazole ring is almost planar (r.m.s. deviation = 0.004 Å) and the prop-2-en-1-yl chain is close to being perpendicular to this plane [C—N—C—C torsion angle = 77.1 (5)°]. In the crystal, centrosymmetric dimeric aggregates are formed by pairs of N—H...S hydrogen bonds as parts of eight-membered (...HNCS)₂ synthons. These are connected into layers parallel to (101) via C—H...π inter­actions, where the π-system is the triazole ring. The investigated sample was a nonmerohedral twin; the refined domain ratio was 0.655 (4):0.345 (4).

1-(Adamantan-1-yl)-3-(4-fluoro­phen­yl)thio­urea

In the title mol­ecule, C₁₇H₂₁FN₂S, the mean planes of the benzene ring and the thio­urea fragment form a dihedral angle of 61.93 (9)°. In the crystal, pairs of weak N—H...S inter­actions link the mol­ecules, forming inversion dimers.