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In the title compound, C14H10Cl2N2O2, the configuration about the C=N double bond is E and the dihedral angle between the benzene rings is 1.75 (5)°. An intra­molecular N—H...O inter­action generates an S(6) ring. In the crystal, mol­ecules are linked by N—H...O hydrogen bonds, resulting in [101] chains.

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In the title compound, C26H23ClFN5O2S2, the mean plane of the guanidine fragment makes dihedral angles of 58.94 (13), 78.37 (17) and 50.76 (15)°, respectively, with the attached thia­zole, pyridine and phenyl rings. The crystal structure features N—H...S and C—H...O hydrogen bonds and weak π–π stacking inter­actions [centroid–centroid separation = 3.7702 (17) Å]. The terminal methyl group of the eth­oxy­carbonyl group is disordered over two orientations in a 0.836 (10):0.164 (10) ratio.

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In the title compound, C9H12N2O, the mean plane through the amide group and the benzene ring form a dihedral angle of 33.93 (7)°. An intra­molecular N—H...O hydrogen bond is present. In the crystal, mol­ecules are linked by N—H...N and N—H...O hydrogen bonds, forming double-stranded chains parallel to the b axis.
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