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In the title compound, C38H32O4P2·2H2O, the dihedral angle between the meth­oxy­phenol rings is 84.11 (7)°. O—H...O hydrogen bonds connect the water mol­ecules of crystallization with the main mol­ecule.

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The supra­molecular structure of the title compound, C9H11N3O3S2, is defined by two inter­molecular hydrogen bonds. Pairs of N—H...N hydrogen bonds link the mol­ecules into centrosymmetric dimers and N—H...O hydrogen bonds link the dimers into a tubular chain structure running parallel to the a axis.
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