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The hydro­thermally prepared title compound, {[Cu3Mo2(NO3)2O8(C10H8N2)3]·4H2O}n, is a hybrid organic/inorganic polymer containing a 16-atom ring built up from molybdate anions, nitrate ions and copper cations. This inorganic network is crosslinked by infinite linear 4,4′-bpy-bridged copper chains (4,4′-bpy is 4,4'-bipyridine) to form channels along the c axis containing the disordered non-coordinated water mol­ecules.
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