metal-organic compounds
In the title complex, [Co(C5H4N2O3)6](ClO4)2, six 4-nitropyridine N-oxide (npo) ligands coordinate to the CoII atom via their N-oxide O atoms, resulting in an octahedral CoO6 grouping. The CoII ion occupies an inversion centre. A short contact of 2.841 (12) Å is observed between a pyridine N atom and a perchlorate O atom.