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The title compound, {[Mg(C2H5NO2)(H2O)4](NO3)2}n, contains cis-MgO2(H2O)4 octa­hedra, which are connected by the glycine mol­ecules to form helical chains. It is isostructural with its cobalt and nickel analogues.

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The title compound, {[Ni(C2H5NO2)(H2O)4](NO3)2}n, contains cis-NiO2(H2O)4 octa­hedra linked by the glycine mol­ecules into helical chains. Its structural relationship to other glycine metal nitrates is discussed.
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