Porous solvent-free μ₂-bis­(salicyl­idene)propane-1,3-diaminato-bis­{[bis­(salicyl­idene)propane-1,3-diaminato]iron(III)}

The title compound, [Fe₂(C₁₇H₁₆N₂O₂)₃], was isolated from the reaction between iron(III) perchlorate hydrate and a mixture of 1,3-bis­(salicylideneamino)propane and triethyl­amine in ethanol. Recrystallization from a dichloro­ethane solution resulted in a porous solvent-free array of mol­ecules. The molecule lies on a special position with twofold symmetry.

N-(4-Methoxy­benzo­yl)-N'-[2-(morpholinium-1-yl)eth­yl]thio­urea thio­cyanate

The title compound {systematic name: 4-[2-({[(4-methoxy­benzo­yl)amino]carbonothio­yl}amino)eth­yl]morpholin-4-ium thio­cyanate}, C₁₅H₂₂N₃O₃S⁺·NCS^-, is a p-anisoylthio­urea salt with a protonated morpholine group and a thio­cyanate counter-anion. The morpholinium group has a chair conformation and the dihedral angle between the p-aniso­yl group and the central thio­urea N₂CS group is 32.51 (8)°. The crystal structure is stablized by intra- and inter­molecular hydrogen bonds.