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The title compound, [Mg(C12H10O4P)(C3H7NO)4](CF3O3S), consists of diphen­ylphosphate anions linked into infinite chains by bridging magnesium ions, which are also coordinated by dimethyl­formamide mol­ecules. A non-coordinated trifluoro­methane­sulfonate counter-ion provides charge balance. Both crystallographically distinct magnesium cations occupy special positions with \overline{1} site symmetry.
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