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In the title compound, (C8H8N4)[ReCl6]·2H2O, the Re atom occupies an inversion centre and is octahedrally coordinated by chloride anions. The cation also has an inversion centre. Various N—H...O, O—H...Cl and C—H...Cl interactions help to stabilize the crystal packing.

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The crystal structure of 4-acetyl­pyridinium chloride, C7H8NO+·Cl, consists of organic layers and Cl anions, which lie within these layers. A hydrogen-bonding network of N—H...Cl inter­actions stabilizes the structure.

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The asymmetric unit of the title compound, (C12H13N2)2[ReO4]I3, contains two 4,4′-dimeth­yl-2,2′-bipyridinium cations, one ReO4 anion and two half-triiodide anions, each anion lying on a centre of symmetry. The crystal packing is stabilized by N—H...O, C—H...O and C—H...I inter­actions.
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