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The crystal structure of the title complex, Na2+·C9H12N3O8P-·6.07H2O·0.27CH4O, in space group P212121 is remarkably similar to the monoclinic P21 structure of sodium cytidine-5'-monophosphate 6.5 hydrate [Borodi et al. (2001). Acta Cryst. E57, m514-m516].

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Two independent molecules in the crystal structure of the title nucleoside, 1-(2-de­oxy-α-D-ribofuranos­yl)-5-methyl­uracil, C10H14N2O5, form a dimer connected by two inter-base hydrogen bonds. The ring puckering modes are envelope C4′-endo and half-chair C3′-exo-C4′-endo, respectively, which are quite uncommon conformations for 2′-deoxy­riboses.
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