metal-organic compounds
Open access
The AuI atom in the title compound, [Au(C6H12NOS)(C18H33P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S—Au—P angle = 173.44 (5)°], with the distortion due in part to a close intramolecular AuO contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.
metal-organic compounds
Open access
The Au atom in the title compound, [Au(C8H7ClNOS)(C18H15P)], exists within a slightly distorted linear geometry defined by an S,P-donor set [S—Au—P angle = 174.61 (4)°], with the distortion related to a short intramolecular AuO contact [2.988 (3) Å]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis by C—Hπ interactions.
metal-organic compounds
Open access
The AuI atom in the title compound, [Au(C9H9ClNOS)(C18H15P)]·0.5CH2Cl2, exists within a slightly distorted linear geometry defined by an S,P donor set [S—Au—P angle = 178.01 (4)°]; a close intramolecular AuO contact [2.964 (4) Å] also occurs. In the crystal structure, molecules are linked into supramolecular chains propagating along [010] by C—HN, C—HS and C—Hπ interactions. The solvent molecule is disordered about a twofold rotation axis.