Download citation
Download citation

link to html
The crystal structure of the room-temperature modification of K[Hg(SCN)3], potassium tri­thio­cyanato­mercurate(II), was redetermined based on modern CCD data. In comparison with the previous report [Zhdanov & Sanadze (1952). Zh. Fiz. Khim. 26, 469–478], reliability factors, standard deviations of lattice parameters and atomic coordinates, as well as anisotropic displacement parameters, were revealed for all atoms. The higher precision and accuracy of the model is, for example, reflected by the Hg—S bond lengths of 2.3954 (11), 2.4481 (8) and 2.7653 (6) Å in comparison with values of 2.24, 2.43 and 2.77 Å. All atoms in the crystal structure are located on mirror planes. The Hg2+ cation is surrounded by four S atoms in a seesaw shape [S—Hg—S angles range from 94.65 (2) to 154.06 (3)°]. The HgS4 polyhedra share a common S atom, building up chains extending parallel to [010]. All S atoms of the resulting 1[HgS2/1S2/2] chains are also part of SCN anions that link these chains with the K+ cations into a three-dimensional network. The K—N bond lengths of the distorted KN7 polyhedra lie between 2.926 (2) and 3.051 (3) Å.

Download citation
Download citation

link to html
The crystal structure of [NiHg(SCN)4(CH3OH)2]n is made up of HgS4 tetra­hedra and trans-NiN4O2 octa­hedra, linked together by thio­cyanato bridges. The methanol mol­ecules point to the cavities of the resulting framework.
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds