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The title mol­ecule, C18H14Cl2, lies about an inversion centre. The hexa­triene chain is planar with a maximum deviation of 0.0001 (17) Å. The torsion angle of the single bond between the chain and the benzene ring is -168.49 (17)°. In the crystal, the shortest inter­molecular distance between the Cl atoms is 4.0785 (11) Å.

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In the title Schiff base compound, C10H12BrN3OS, the C-N-N-C torsion angle is 172.07 (11)°. An intra­molecular hydrogen bond exists between the hy­droxy H atom and the azomethine N atom. In the crystal, pairs of hydrogen bonds involving the imino H atom and the S atom give rise to supra­molecular dimers.
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