organic compounds
Open access
The title compound, C16H20N4OS2, was synthesized by the reaction of 2-benzylsulfanyl-5-chloroacetamido-1,3,4-thiadiazole and piperidine in a 1:2 ratio. The planes of the acetamide and 1,3,4-thiadiazole units are twisted by 10.8 (4)°. The thiadiazole S atom and the acetamide O atom are syn-oriented due to a hypervalent SO interaction of 2.628 (4) Å. In the crystal, molecules form centrosymmetric dimers via N—HN hydrogen bonds. These dimers are further connected by C—HO interactions into (100) layers.