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In the crystal structure of the title compound, C14H15BrO2, weak C—H...O inter­actions link the mol­ecules into zigzag chains extending along the c-axis direction. These chains are further assembled into (100) layers via π–π stacking inter­actions between inversion-related chromenone fragments [inter­planar distance = 3.376 (2) Å].

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In the mol­ecule of the title compound, C11H6F3N3O, the three fused rings of the benzo[4,5]imidazo[1,2-a]pyrimidine unit are essentially coplanar, the maximum deviation from the mean plane being 0.096 (2) Å. In the crystal, N—H...O hydrogen bonds link the mol­ecules into chains running along the b-axis direction.
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