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In the title co-crystal, C12H11Br2N3O·C4H5NO2, the naphthyridine derivative and the pyrrolidine-2,5-dione mol­ecules have crystallographic mirror-plane symmetry with all non-H atoms, except the Br atom, located on the mirror plane. In the crystal, N—H...N, N—H...O and C—H...O hydrogen bonds link the mol­ecules into heterodimers. These dimers are further linked into a one-dimensional structure along [010] by weak C—Br...O inter­actions [Br...O = 3.028 (5) Å and C—Br...O = 158.52 (4)°].

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In the title complex, [Cu(NO3)2(C10H8N2)], the CuII cation is chelated by two nitrate anions and by one 2,2′-bi­pyridine ligand in a distorted N2O4 octa­hedral geometry. The dihedral angle between the pyridine rings is 1.92 (11)°. In the crystal, π–π stacking between parallel pyridine rings of adjacent complex mol­ecules is observed, the centroid–centroid distance being 3.6788 (19) Å. Weak C—H...O hydrogen bonds further link the mol­ecules into a three-dimensional supra­molecular architecture.

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In the anion of the title compound, NH4+·C16H13O3·2H2O, the benzene rings are twisted with respect to each other by 73.56 (10)°. In the crystal, extensive N—H...O and O—H...O hydrogen bonds link the cations, anions and lattice water mol­ecules into a three dimensional supra­molecular structure.
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