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In the crystal structure of title compound, C9H10N2OS, there are two symmetry-independent molecules, each having an intramolecular N—H
O hydrogen bond generating an S(6) ring motif. The benzene rings and the virtually planar acetylthoiurea fragments [r.m.s. deviations = 0.0045 and 0.0341 Å] are oriented at dihedral angles of 50.71 (6) and 62.79 (6)° in the two molecules. In the crystal, N—HS and N—HO hydrogen bonds link molecules via cyclic R22(8) and R22(12) motifs into a one-dimensional polymeric network extending along [101]. The intra- and intermolecular N—HO interactions are part of a three-center hydrogen bond. A C—HS interaction also occurs.
O hydrogen bond generating an S(6) ring motif. The benzene rings and the virtually planar acetylthoiurea fragments [r.m.s. deviations = 0.0045 and 0.0341 Å] are oriented at dihedral angles of 50.71 (6) and 62.79 (6)° in the two molecules. In the crystal, N—HS and N—HO hydrogen bonds link molecules via cyclic R22(8) and R22(12) motifs into a one-dimensional polymeric network extending along [101]. The intra- and intermolecular N—HO interactions are part of a three-center hydrogen bond. A C—HS interaction also occurs.organic compoundsOpen access
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In the title compound, C10H12N2OS, the toluene and the N-carbamothioylacetamide units are oriented at dihedral angle of 78.75 (5)°. An intramolecular N—HO hydrogen bond generates an S(6) ring. In the crystal, molecules are linked into [101] chains by pairs of N—HS hydrogen bonds [which generate R22(8) loops] and pairs of O—HO hydrogen bonds [which generate R22(4) loops]. The two motifs alternate in the chain.
O hydrogen bond generates an S(6) ring. In the crystal, molecules are linked into [101] chains by pairs of N—HS hydrogen bonds [which generate R22(8) loops] and pairs of O—HO hydrogen bonds [which generate R22(4) loops]. The two motifs alternate in the chain.organic compoundsOpen access
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In the title compound, C9H9ClN2OS, the 3-chlorophenyl and acetylthiourea fragments are oriented at a dihedral angle of 62.68 (5)°. An intramolecular N—HO hydrogen bond generates an S(6) ring motif. Molecules are linked into dimers via a cyclic R22(8) motif of N—HS hydrogen bonds. These dimers are further connected through C—HS interactions, completing an R22(12) motif, into chains along [010].
O hydrogen bond generates an S(6) ring motif. Molecules are linked into dimers via a cyclic R22(8) motif of N—HS hydrogen bonds. These dimers are further connected through C—HS interactions, completing an R22(12) motif, into chains along [010].organic compoundsOpen access
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In the title compound, C9H9N3O3S, the benzene ring and the N-carbamothioylacetamide unit are oriented at a dihedral angle of 54.82 (4)°. The dihedral angle between the ring and its attached nitro group is 28.54 (12)°. An intramolecular, bifurcated N—H(O,O) hydrogen bond generates two S(6) rings. In the crystal, inversion dimers linked by pairs of N—HS hydrogen bonds generate R22(8) loops. Weak C—HO interactions link the dimers.
(O,O) hydrogen bond generates two S(6) rings. In the crystal, inversion dimers linked by pairs of N—HS hydrogen bonds generate R22(8) loops. Weak C—HO interactions link the dimers.
