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In the title dinuclear nickel(II) complex, [Ni2(C8H4FO3)2(H2O)4]Cl2, synthesized by the reaction between 4-fluoro-2,6-diformyl­phenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the NiII atom adopts a slightly distorted octa­hedral coordination geometry. The two Ni atoms are bridged by two phenolate O atoms and the intra­molecular Ni...Ni distance is 3.0751 (9) Å. The crystal structure is stabilized by O—H...Cl hydrogen bonds.
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