metal-organic compounds
Tetraaqua(18-crown-6)cerium(III) hexacyanoferrate(III) dihydrate, [Ce(C12H24O6)(H2O)4][Fe(CN)6]·2H2O, and tetraaqua(18-crown-6)neodymium(III) hexacyanoferrate(III) dihydrate, [Nd(C12H24O6)(H2O)4][Fe(CN)6]·2H2O, are isomorphous and isostructural in the C2/c space group, where the cations, which contain ten-coordinate lanthanoid centres, lie across twofold rotation axes and the anions lie across inversion centres. In these compounds, an extensive series of O—HO and O—HN hydrogen bonds links the components into a continuous three-dimensional framework. Triaqua(18-crown-6)lanthanoid(III) hexacyanoferrate(III) dihydrate, [Ln(C12H24O6)(H2O)3][Fe(CN)6]·2H2O, where Ln = Sm, Eu, Gd or Tb, are all isomorphous and isostructural in the P space group, as are triaqua(18-crown-6)gadolinium(III) hexacyanochromate(III) dihydrate, [Gd(C12H24O6)(H2O)3][Cr(CN)6]·2H2O, and triaqua(18-crown-6)gadolinium(III) hexacyanocobaltate(III) dihydrate, [Gd(C12H24O6)(H2O)3][Co(CN)6]·2H2O. In these compounds, there are two independent anions, both lying across inversion centres, and the lanthanoid centres exhibit nine-coordination; in the crystal structures, an extensive series of hydrogen bonds links the components into a three-dimensional framework.