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The mol­ecule of the title compound, C9H9N5O, is essentially planar (r.m.s. deviation of all atoms = 0.02 Å) except for the NH2 H atoms. An intra­molecular hydrazinyl­idene–carbonyl N—H...O=C hydrogen bond is present. In the crystal, mol­ecules are connected via N—H...N/O hydrogen bonds, forming thick layers parallel to (100).
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