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In the title compound, [Na(C5H5N4O3)]·2H2O, each Na cation is linked to three C5H4N4O3 anions and two water mol­ecules, forming approximately octahedral NaNO5 units; the cations and the anions form molecular ladders, and each ladder is linked to four neighbouring ladders by O—H...O and O—H...N hydrogen bonds.
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