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In the title compound, C6H8N2O2S, also known as N-acetyl-2-thio­hydantoin–alanine, the mol­ecules are joined by N—H...O hydrogen bonds, forming centrosymmetric R22(8) dimers; these dimers are linked by C—H...O inter­actions to form R22(10) rings, thus forming C22(10) chains that run along the [101] direction.
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