metal-organic compounds
1-[6-(1H-Pyrrolo[2,3-b]pyridin-1-yl)pyridin-2-yl]-1H-pyrrolo[2,3-b]pyridin-7-ium tetrachloridoferrate(III), (C19H14N5)[FeCl4], (II), and [2,6-bis(1H-pyrrolo[2,3-b]pyridin-1-yl-κN7)pyridine-κN]bis(nitrato-κO)copper(II), [Cu(NO3)2(C19H13N5)], (III), were prepared by self-assembly from FeCl3·6H2O or Cu(NO3)2·3H2O and 2,6-bis(1H-pyrrolo[2,3-b]pyridin-1-yl)pyridine [commonly called 2,6-bis(azaindole)pyridine, bap], C19H13N5, (I). Compound (I) crystallizes with Z′ = 2 in the P space group, with both independent molecules adopting a trans–trans conformation. Compound (II) is a salt complex with weak C—HCl interactions giving rise to a zigzag network with π-stacking down the a axis. Complex (III) lies across a twofold rotation axis in the C2/c space group. The CuII center in (III) has an N3O2 trigonal–bipyramidal environment. The nitrate ligand coordinates in a monodentate fashion, while the bap ligand adopts a twisted tridentate binding mode. C—HO interactions give rise to a ribbon motif.